Why 'white rust' Forms
Galvanized steel is protected from corrosion by the formation of a protective zinc carbonate film over the zinc surface. In order to form, exposure is required to free flowing air. Freshly galvanized articles that are stacked in contact with one another, so preventing the free circulation of air may, in wet or humid conditions, start to show “white rust”. This is a white powdery covering of a mixture of zinc oxide and zinc hydroxide. As this is unable to stabilise, in poorly ventilated packing, the protective zinc carbonate film does not form and the reaction on the zinc surface continues. White rust is voluminous and, as a result, often looks worse than it actually is. However, conditions which encourage its formation should not be allowed to persist.